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Why LGM methane needs a bigger wetland collapse

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Ice-core CH4 and isotopes imply about a 50% source drop at the LGM; process models underpredict both concentration and isotopic shifts.

Source

Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling

Hopcroft PO, Valdes PJ, Kaplan JO · Geophysical research letters · 2018

doi.org/10.1002/2018gl077382Read the full paper ↗5 citationscc by

Study at a glance

Design
Computational / modelling — MCMC inversion of LGM vs preindustrial CH4 and isotopes in a three-box model
N
Ice-core constraints and Earth-system flux priors; not an observational sample N
Population
Atmospheric methane budget from LGM to late preindustrial (ice-core constrained)
Outcome
Required source reductions and isotope shifts poorly matched by process models

Structured fields used in claim comparison tables when every cited study has a complete layer.

What they did

Authors nested Hopcroft et al. Earth-system methane budgets in a three-box isotope model, added leaf-δ13C and chlorine sinks, then used MCMC to invert LGM versus preindustrial ice-core CH4, δ13C, and δD.

What they found

CH4 rose from 375 to 680 ppbv while δ13CH4 fell from −43 to −48‰. Standard LGM fluxes give 447 ppbv and almost no isotope shift. Leaf discrimination adds only ~0.6‰. Posterior wetlands must fall more than models simulate; geologic and fire sources also matter.

The limits

What it doesn't show

High-latitude peat and CH3Cl sources remain poorly represented; a 54 Tg/yr modern geologic source cannot fit the LGM reduction; Cl from extra LGM sea salt is not in the model.

Key terms

LGM
Last Glacial Maximum, the last peak ice-age climate.
δ13CH4
Carbon-13 composition of atmospheric methane.
Three-box model
Simple atmosphere used to mix methane sources and sinks isotopically.
Wetland methane
Biogenic CH4 from inundated soils, the largest natural source.
MCMC
Markov chain Monte Carlo sampling of posterior source strengths.

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LGM to preindustrial CH4:

Common questions

LGM vs preindustrial CH4?

About 375 to 680 ppbv.

Needed source change?

About a 50% reduction at the LGM.

Do bottom-up models match isotopes?

No—they underpredict concentration and isotope shifts.

Leaf δ13C role?

Limited (~0.6‰ of the atmospheric signal).

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