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Atmospheric chemistry

South African ozone peaks with fires and winter fires

Laban TL, van Zyl PG, Beukes JP, et al. · Atmospheric chemistry and physics · 2018

Open access · cc by · source: Europe PMC

Continental South African surface ozone peaks in late winter–spring from household combustion and biomass burning, and is often VOC-limited.

Key findings

Sites regularly exceed the South African ozone standard. Concentrations peak in late winter and early spring: winter trapping of household-combustion pollution plus a spring biomass-burning CO source. Stratospheric intrusions are minor. Ozone correlates with CO more than NOx, and at least 40% of Welgegund production is VOC-limited amid high regional NOx.

Methodology

Authors analyzed continuous in situ ozone at Botsalano, Marikana, Welgegund, and Elandsfontein, related it to NOx and CO, used air-mass origin, and computed ozone production regime from a 2-year VOC dataset at Welgegund.

Limitations

VOC-limited inference is strongest at Welgegund; the other sites lack the same VOC record. The paper is observational, not a full photochemical-model source apportionment, and socio-economic household burning is hard to regulate from this evidence alone.

How this study connects

Role on claims

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  • SupportsAtmospheric chemistryconcept

    Continental South African surface ozone peaks in late winter–spring from household combustion and biomass burning, and is often VOC-limited.

    Evidence for the claim as stated.

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