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Vanadium nitrogenase fuels forest moss N fixation

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Vanadium nitrogenase was active in most valid moss and lichen samples across three continents, averaging about 40% of moss N2 fixation.

Source

Global Role of Vanadium for Cryptogamic Nitrogen Fixation in Extratropical Forests

Darnajoux R, Haynes SJ, Renaudin M, et al. · Environmental science & technology · 2026

doi.org/10.1021/acs.est.5c12982Read the full paper ↗1 citationscc by

Study at a glance

Design
Cross-sectional — LISARA assays of moss and lichen V-nitrogenase across three continents
N
N=109 · 109 sampling plots (>40 sites, 9 locations); multiple cryptogam samples per plot
Population
Mosses and lichens in extratropical forests of North America, South America, and East Asia
Outcome
Share of biological N2 fixation attributable to vanadium nitrogenase

Structured fields used in claim comparison tables when every cited study has a complete layer.

What they did

Used low-activity isotopic acetylene reduction (LISARA) on cryptogams from over 40 sites in 9 locations across North America, South America, and East Asia.

What they found

V-Nase occurred in 68±20% of samples by site (79% of valid assays), 15 of 28 genera, from 28% of Hokkaido samples to 94% in North Carolina; mosses ~40% and lichens ~25% of BNF.

The limits

What it doesn't show

Isotopes cannot yet separate V-only from Fe-only nitrogenase, and assays do not scale measured rates to a global N budget.

Key terms

V-Nase
Vanadium-based alternative nitrogenase used when molybdenum is scarce.
BNF
Biological nitrogen fixation converting N2 into biologically available N.
LISARA
Low-activity isotopic acetylene reduction assay that distinguishes Mo vs alternative nitrogenases.
Cryptogams
Mosses, lichens, and similar non-seed covers that host N-fixing microbes.
Mo-Nase
Canonical molybdenum nitrogenase, the textbook N2-fixing enzyme.
Acetylene reduction
Proxy assay in which nitrogenase reduces acetylene to ethylene.

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Sampling scope:

Common questions

Sites?

Over 40 sites, 9 locations, 3 continents.

Positive V-Nase share?

68±20% of samples by location; 79% of valid assays.

Moss vs lichen V share?

About 40% vs 25% of specimen BNF.

Genera with V-Nase?

15 of 28 tested.

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