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Serum phthalates track adipose redox markers

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In 308 Spanish adults, low-molecular-weight phthalates associated with higher GPx and TBARS in fat, while a phthalate mixture index associated with lower GSH and GSSG.

Source

Serum Phthalate Concentrations and Biomarkers of Oxidative Stress in Adipose Tissue in a Spanish Adult Cohort

Pérez-Díaz C, Pérez-Carrascosa FM, Riquelme-Gallego B, et al. · Environmental science & technology · 2024

doi.org/10.1021/acs.est.3c07150Read the full paper ↗10 citationscc by

Study at a glance

Design
Cross-sectional — GraMo surgery patients with serum phthalates and adipose oxidative-stress biomarkers
N
N=308 · 308 with adipose redox markers; 143 with overlapping exposure and markers; 230 with serum phthalates
Population
Spanish adults undergoing surgery in the GraMo study
Outcome
Adipose oxidative-stress biomarkers associated with serum phthalates and mixtures

Structured fields used in claim comparison tables when every cited study has a complete layer.

What they did

GraMo surgery patients had 32 serum phthalate metabolites measured by LC–MS/MS and nine oxidative-stress biomarkers assayed in adipose; robust regression and weighted quantile sum (WQS) mixture models were fit.

What they found

MEP was the most abundant metabolite. Several LMWP metabolites (MMP, MiBP, MnBP) associated positively with GPx and TBARS, whereas HMWP MiNP associated negatively. The WQS index associated with lower GSH (β = −30.089) and GSSG (β = −19.591); MEHP and MECPP dominated the GSH mixture.

The limits

What it doesn't show

Cross-sectional surgery sample cannot establish temporality; adipose 8OHdG was only available for 112 people; short-lived phthalates make a single serum sample a noisy exposure metric.

Key terms

Phthalates
Plasticizer chemicals grouped as low- vs high-molecular-weight parent diesters.
LMWP vs HMWP
Low- vs high-molecular-weight phthalates used in cosmetics vs PVC plasticizers.
GPx / TBARS
Glutathione peroxidase activity and lipid-peroxidation products in adipose.
WQS index
Weighted quantile sum mixture score of co-occurring phthalate metabolites.
GraMo cohort
Granada surgical patients providing adipose and serum for pollutant studies.

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Adipose redox markers were measured in how many people?

Common questions

How many people had adipose redox markers?

308 participants; 143 had both exposure and markers overlapping as described.

Which metabolite was highest?

MEP, then MMP.

LMWP vs GPx/TBARS?

Positive associations.

Mixture effect on GSH?

Negative WQS association (p = 0.025).

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